SAFETY DATA SHEET
OSHA HCS (29 CFR 1910.1200)
1. Identification
Product identifier
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Date
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04/18/2018
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Product name
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Gem Rust Killer And Metal Prep
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Chemical Name
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Mixture
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Recommended use of the chemical and restrictions on use
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Application
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Rust remover/converter
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Uses advised against
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May be corrosive to metals
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Details of the supplier of the safety data sheet
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Supplier
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BALANDIS CHEMICAL CO. LLC
P.O. Box 31104
HOUSTON, TX 77035
713-723-6524
www.gemrustkiller.com
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Emergency telephone number
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Emergency telephone
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PERS emergency response number: 1-800-633-8253 (Contract #9390)
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2. Hazard(s) identification
Classification of the substance or mixture
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Physical hazards
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Flam. Liq. 4 - H227 Met. Corr. 1 - H290
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Health hazards
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Skin Corr. 1B - H314 Eye Dam. 1 - H318
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Label elements
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Pictogram
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Signal word
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Danger
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Hazard statements
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H227 Combustible liquid. H290 May be corrosive to metals.
H314 Causes severe skin burns and eye damage.
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Precautionary statements
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P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. P234 Keep only in original container.
P260 Do not breathe vapor/spray.
P264 Wash contaminated skin thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated
clothing. Rinse skin with water/shower.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
P321 Specific treatment (see medical advice on this label).
P363 Wash contaminated clothing before reuse.
P370+P378 In case of fire: Use foam, carbon dioxide, dry powder or water fog to
extinguish. P390 Absorb spillage to prevent material damage.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner liner.
P501 Dispose of contents/container in accordance with national regulations.
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3. Composition/information on ingredients
Hazardous Ingredient(s)
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Phosphoric acid
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7664-38-2 (231-633-2)
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30 - 50% Corrosive to metals - Cat 1 Skin corrosion - Cat 1B
Serious eye damage - Cat 1
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Proprietary Glycol Ethers
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Proprietary
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0.1 - 5% Acute Tox Oral - Cat. 4 Acute Tox Inhalation - Cat 4
Acute Tox Dermal - Cat 4 Skin irritation - Cat 2 Eye irritation - Cat 2A
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Composition comments
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The Full Text for all Hazard Statements is Displayed in Section 16. The exact percentage
withheld as a trade secret in accordance with 29 CFR 1910.1200.
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4. First-aid measures
Description of first aid measures
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General information
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Move affected person to fresh air at once. Consult a physician for specific advice.
Show this Safety Data Sheet to the medical personnel.
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Inhalation
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Move affected person to fresh air and keep warm and at rest in a position comfortable
for breathing. Get medical attention if any discomfort continues.
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Ingestion
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Do not induce vomiting unless under the direction of medical personnel. Never give anything
by mouth to an unconscious person. Get medical attention.
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Skin Contact
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Get medical attention immediately. It is important to remove the substance from the skin
immediately. Rinse immediately with plenty of water.
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Eye contact
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Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do.
Continue rinsing. Get medical attention if symptoms are severe or persist after washing.
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5. Fire-fighting measures
Extinguishing media
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Suitable extinguishing media
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Extinguish with alcohol-resistant foam, carbon dioxide, dry powder or water fog.
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Unsuitable extinguishing media
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None known.
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Special hazards arising from the substance or mixture
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Flammability Class
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3.2 Combustible Liquid IIIB.
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Specific hazards
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Combustible liquid.
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Hazardous combustion products
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Toxic gases or vapors. Carbon dioxide (CO2). Carbon monoxide (CO).
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Advice for fire fighters
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Protective actions during fire fighting
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If involved in a fire, shut off flow if it can be done without risk. Fight fire with normal
precautions from a reasonable distance. Control run-off water by containing and keeping
it out of sewers and watercourses.
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Special protective equipment for fire fighters
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Wear positive-pressure self-contained breathing apparatus (SCBA) and appropriate protective clothing.
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6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Personal precautions
No smoking, sparks, flames or other sources of
ignition near spillage. Keep unnecessary and unprotected personnel away from the
spillage. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapors.
Environmental precautions
Environmental precautions
The product
contains substances which are water-soluble and may spread in water systems.
Methods and material for containment and cleaning up
Methods for cleaning up
Absorb in vermiculite, dry sand or earth and place
into containers.
7. Handling and storage
Precautions for safe handling
Usage precautions
Avoid exposure - obtain special instructions before use.
Avoid contact with skin, eyes and clothing. Do not breathe vapor/spray. Use only
outdoors or in a well-ventilated area. Do not spray on an open flame or other
ignition source. Pressurized container: Do not pierce or burn, even after use.
Conditions for safe storage, including any incompatibilities
Storage precautions
Store in a cool and well-ventilated place.
Protect from sunlight. Store at temperatures not exceeding 50°C/122°F.
Specific end uses(s)
Specific end uses(s)
The identified uses for this product are detailed in Section 1.2.
8. Exposure Controls/personal protection
Control parameters
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Occupational exposure limits
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Phosphoric acid
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TWA
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1 mg/m3 - ACGIH
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STEL
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3 ppm - ACGIH
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TWA
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1 mg/m3 - OSHA Z-1
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TWA
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1 mg/m3 - OSHA PO
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STEL
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3 mg/m3 - OSHA PO
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Proprietary Glycol Ethers
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TWA
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5ppm - ACGIH
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TWA
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50 ppm - OSHA Z-1
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TWA
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24 ppm - OSHA PO
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Exposure controls
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Protective equipment
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Eye/face protection
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Wear eye protection. Wear tight-fitting, chemical splash goggles or face shield.
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Hand protection
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The most suitable glove should be chosen in consultation with the glove
supplier/manufacturer, who can provide information about the breakthrough
time of the glove material.
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Respiratory protection
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Respiratory protection not required.
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Environmental exposure controls
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Keep container tightly sealed when not in use.
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9. Physical and Chemical Properties
Information on basic physical and chemical properties
Appearance: Liquid
Color: Green
Odor: Pungent, acidic
pH: 1
Melting point: No information available.
Initial boiling point and range: 100°C/212°F
Flash point: 62°C/145°F TCC (Tag closed cup).
Evaporation rate: No information available.
Evaporation factor: No information available.
Flammability (solid, gas): No information available.
Upper/lower flammability or explosive limits: Lower: 1.1, Upper: No information available.
Vapor pressure: 17.5 mm Hg @ 20°C
Vapor density: No information available.
Relative density: No information available.
Bulk density: No information available.
Solubility (yes): Soluble in water.
Partition coefficient: No information available.
Auto-ignition temperature: No information available.
Decomposition Temperature: No information available.
Viscosity: No information available.
Explosive properties: No information available.
Explosive under the influence of a flame: Not considered to be explosive.
Oxidizing properties: No information available.
Volatile organic compound: This product contains a maximum VOC content of 12.6 g/l. / 1.4 %.
10. Stability and reactivity
Stability
Stable at normal ambient temperatures and when used as recommended.
Possibility of hazardous reactions
The following materials may react strongly with the
product: Most metals producing hydrogen which is extremely flammable & may explode.
Conditions to avoid
Keep away from heat, sparks and open flame.
Materials to avoid
Alkalis. Amines. May be corrosive to metals.
Hazardous decomposition products
Carbon dioxide (CO2). Carbon monoxide (CO).
Phosphorus Pent oxide from burning.
11. Toxicological information
Information on toxicological effects
Toxicological effects
Chronic overexposure may cause damage to kidneys,
blood, nerves, liver & lungs. Persons with severe skin, liver or kidney problems
should avoid use.
Skin corrosion/irritation
Corrosivity to eyes is assumed.
Serious eye damage/irritation
Corrosivity to eyes is assumed.
Respiratory sensitization
Based on available data the classification criteria are not met.
Skin sensitization
Based on available data the classification criteria
are not met.
Germ cell mutagenicity
Genotoxicity - in vitro
Based on available data the classification criteria
are not met.
Genotoxicity - in vitro
Based on available data the
classification criteria are not met.
Carcinogenicity
Based on
available data the classification criteria are not met.
Reproductive toxicity
Reproductive toxicity - fertility
Based on available data the classification criteria are not met.
Reproductive toxicity - development
This substance has no evidence of
toxicity to reproduction.
Specific target organ toxicity - single exposure
STOT - single exposure
Based on available data the classification
criteria are not met.
Specific target organ toxicity - repeated exposure
STOT - repeated exposure
Based on available data the classification
criteria are not met.
Aspiration hazard
Not relevant.
12. Ecological Information
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Persistence and degradability
Persistence and degradability
The product is biodegradable.
Bioaccumulative potential
Partition coefficient
Not available.
Mobility in soil
Mobility
The product is soluble in water.
13. Disposal considerations
Waste treatment methods
General information
The generation
of waste should be minimized or avoided wherever possible.
Disposal methods
Waste, residues, empty containers, discarded work clothes
and contaminated cleaning materials should be collected in designated containers,
labeled with their contents. Dispose of surplus products and those that cannot be
recycled via a licensed waste disposal contractor.
14. Transport information
Department of Transportation: (DOT)
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UN3264, Corrosive liquid, acidic, inorganic,
N.O.S. (Phosphoric Acid Solution), 8, III
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In 1 Gallon or smaller sizes, this product is considered Limited Quantities
and is Not Regulated by DOT.
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15. Regulatory information
US Federal Regulations
SARA Section 302 Extremely Hazardous Substances Tier II Threshold Planning Quantities
None of the ingredients are listed or exempt.
CERCLA/Superfund, Hazardous Substances/Reportable Quantities (EPA)
CERCLA Reportable Quantities
Phosphoric Acid (7664-38-2) 5000 lbs
SARA (311/312) Hazard Categories:
Acute
Fire
US State Regulations
California Proposition 65 Carcinogens and Reproductive Toxins
None of the
ingredients are listed or exempt.
Massachusetts "Right To Know" List
Some of the ingredients are listed or exempt.
New Jersey "Right To Know" List
Some of the ingredients are listed or exempt.
Pennsylvania "Right To Know" List
Some of the ingredients are listed or exempt.
Inventories
EU - EINECS/ELINCS: All the ingredients are listed or exempt.
Canada - DSL/NDSL: All the ingredients are listed or exempt.
US - TSCA:
All the ingredients are listed or exempt.
Australia - AICS: All the ingredients
are listed or exempt
Japan - MITI: All the ingredients are listed or exempt.
Korea - KECI: All the ingredients are listed or exempt.
China - IECSC:
All the ingredients are listed or exempt.
Philippines - PICCS: All the ingredients
are listed or exempt.
16. Other information
Training advice
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None.
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Revision comments
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The following sections contain revisions or new statements: 1-16.
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SDS status
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Approved.
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Hazard statements in full
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H227 Combustible liquid.
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H290 May be corrosive to metals.
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H302 Harmful if swallowed.
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H312 Harmful in contact with skin.
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H314 Causes severe skin burns and eye damage.
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H315 Causes skin irritation.
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H318 Causes serious eye damage.
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H319 Causes serious eye irritation.
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H332 Harmful if inhaled.
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H335 May cause respiratory irritation.
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NFPA - flammability hazard
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Burns only if pre-heated. (1)
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NFPA - health hazard
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Extremely hazardous, serious injury. (3)
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NFPA - instability hazard
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Normally stable. (0)
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Disclaimer
The supplier disclaims all expressed or implied warranties of merchantability or fitness
for a specific use, with respect to the product or the information provided herein, except
for conformation to contracted specifications. All information appearing herein is based
upon data obtained from manufacturers and/or recognized technical sources. While the information
is believed to be accurate, we make no representations as to its accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for verifying
the data under their own operating conditions to determine whether the product is suitable
for their particular purposes and they assume all risks of their use, handling, and disposal
of the product. Users also assume all risks in regards to the publication or use of, or reliance
upon, information contained herein. This information relates only to the product designated
herein, and does not relate to its use in combination with any other material or process.
Balandis Chemical Co. LLC • PO Box 31104 • Houston,
Texas 77035
information@gemrustkiller.com
Phone (713) 723-6524 • Fax (713) 723-8214